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【人名反应】Eglinton偶联反应

末端炔在化学计量铜盐()存在下,在吡啶中的氧化偶联反应,用于对称二炔和环状二炔的合成。


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反应机理


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反应实例


该反应被成功的用于环状多炔化合物的合成。


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参考文献


1. Eglinton, G. and Galbraith, A. R., Chem. & Ind. (London), 1956, 737.

2. Inouchi, K.; Kobashi, S.; Takimiya, K.; Aso, Y. and Otsubo, T., Org. Lett., 2002, 4, 2533.

3. Tobe, Y.; Kishi, J.-Y.; Ohki, I. and Sonoda, M., J. Org. Chem., 2003, 68, 3330.

4. Hoffmann, B.; Bernet, B. and Vasella, A., Helv. Chim. Acta, 2002, 85, 265.



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