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【人名反应】Dotz反应

从烯基烷氧基五配位的铬卡宾配合物和炔烃合成Cr(CO)3配位的氢醌。


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反应机理


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反应实例






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参考文献


1. Dötz, K. H. Angew. Chem. 1975, 87, 672-673.

2. Dötz, K. H. Angew. Chem., Int. Ed. Engl. 1975, 14,644-645.

3. Dötz, K. H. Angew. Chem. 1979, 91, 1021-1022.

4. Dötz, K. H., Chem. Ber. 1980, 113, 1449-1457.

5. Casey, C. P. Metal-carbene complexes [as reactiveintermediates]. Reactive Intermediates (Wiley) 1981, 2, 135-174.

6. Tang, P. C., Wulff, W. D. J. Am. Chem. Soc. 1984, 106,1132-1133.

7. Merlic, C. A., Aldrich, C. C., Albaneze-Walker, J.,Saghatelian, A., Mammen, J. J. Org. Chem. 2001, 66, 1297-1309.

8. King, J., Quayle, P., Malone, J. F. Tetrahedron Lett.1990, 31, 5221-5224.

9. Pulley, S. R., Carey, J. P. J. Org. Chem.1998, 63,5275-5279.


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